Photochemistry of Transition Metal Coordination Compounds
نویسنده
چکیده
منابع مشابه
Photochemistry and photophysics of coordination compounds of the main group metals
The photoproperties of main group metal complexes with the electron configurations s2 (e.g. Tl+, Sb3+, Te4+) and so (e.g. T13+, Pb4+) were studied on the basis of a general concept which relates characteristic excited states to typical photophysical and photochemical processes. The photochemistry is dominated by metalcentered sp (s2) and ligand to metal charge transfer (so) excited states which...
متن کاملPhotochemical Reductive Elimination of TetrachloroiodateQII)
In analogy to transition metal complexes, coordination compounds of the main group metals can be also classified according to the electron configuration at the metal. Generally, the main group metals occur in oxidation states with so, s2, s2p2 and s2p4 ground states. Recently, we studied the photolysis of so and s2 systems [l-4]. We now report the first results on the photochemistry of an s2p2 ...
متن کاملUpconverting nanoparticles for the near infrared photoactivation of transition metal complexes: new opportunities and challenges in medicinal inorganic photochemistry.
The article highlights the emergent use of upconverting nanoparticles as tools for the near infrared photoactivation of transition metal complexes, identifying opportunities and challenges of this approach in the context of medicinal inorganic chemistry.
متن کاملPhotochemistry of Carbonyl Complexes
The photosensitivity of metal carbonyls has been known almost as long as the class of coordination compounds itself. Among no other group of inorganic compounds may one find so many light-sensitive materials. Hence photochemical reactions of metal carbonyls have found wide applications for synthetic purposes. However, whereas much research has been done to understand the thermal reactions," the...
متن کاملThe photochemistry of transition metal complexes using density functional theory.
The use of density functional theory (DFT) and time-dependent DFT (TD-DFT) to study the photochemistry of metal complexes is becoming increasingly important among chemists. Computational methods provide unique information on the electronic nature of excited states and their atomic structure, integrating spectroscopy observations on transient species and excited-state dynamics. In this contribut...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2008